CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not
available or no answer, refer to appropriate telephone number listed on the inside back cover.
As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50
meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
Keep unauthorized personnel away.
Stay upwind.
Keep out of low areas.
Ventilate enclosed areas.
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PROTECTIVE CLOTHING
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Wear positive pressure self-contained breathing apparatus (SCBA).
Wear chemical protective clothing that is specifically recommended by the manufacturer. It may
provide little or no thermal protection.
Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is
not effective in spill situations where direct contact with the substance is possible.
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EVACUATION
Spill
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See the Table of Initial Isolation and Protective Action Distances for highlighted substances. For
non-highlighted substances, increase, in the downwind direction, as necessary, the isolation
distance shown under "PUBLIC SAFETY".
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Fire
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If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all
directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.
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FIRE
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Note: Most foams will react with the material and release corrosive/toxic gases.
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Small Fires
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CO2 (except for Cyanides), dry chemical, dry sand, alcohol-resistant foam.
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Large Fires
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Water spray, fog or alcohol-resistant foam.
Move containers from fire area if you can do it without risk.
Use water spray or fog; do not use straight streams.
Dike fire-control water for later disposal; do not scatter the material.
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Fire involving Tanks or Car/Trailer Loads
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Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
Do not get water inside containers.
Cool containers with flooding quantities of water until well after fire is out.
Withdraw immediately in case of rising sound from venting safety devices or discoloration of
tank.
ALWAYS stay away from tanks engulfed in fire.
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SPILL OR LEAK
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ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
All equipment used when handling the product must be grounded.
Do not touch damaged containers or spilled material unless wearing appropriate protective
clothing.
Stop leak if you can do it without risk.
A vapor suppressing foam may be used to reduce vapors.
DO NOT GET WATER INSIDE CONTAINERS.
Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to
contact spilled material.
Prevent entry into waterways, sewers, basements or confined areas.
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Small Spills
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Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet
to minimize spreading or contact with rain.
Use clean non-sparking tools to collect material and place it into loosely covered plastic
containers for later disposal.
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FIRST AID
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Move victim to fresh air.
Call 911 or emergency medical service.
Give artificial resipiration if victim is not breathing.
Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial
respiration with the aid of a pocket mask equipped with a one-way valve or other proper
respiratory medical device.
Administer oxygen if breathing is difficult.
Remove and isolate contaminated clothing and shoes.
In case of contact with substance, immediately flush skin or eyes with running water for at least
20 minutes.
For minor skin contact, avoid spreading material on unaffected skin.
Keep victim warm and quiet.
Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.
Ensure that medical personnel are aware of the material(s) involved and take precautions to
protect themselves.
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Data Source for our online 2004 ERG
This information was compiled from the 2004 Emergency Response Guidebook (2004 ERG) which
is produced by the U.S. Department of Transportation.
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